Georgia Steel put the cat between pigeons on Monday's episode of Love Island All Stars when she asked Molly Smith if she had ever kissed new bombshell Joe Garratt.
A teaser at the end of the episode showed the Islanders playing a heated icebreaker game, scenes of which will air in Tuesday's episode.
After arriving at the villa with twins Jess and Eve Gale, 29-year-old Joe set about getting to know the residents better.
As part of the challenge, participants were asked: “Snog the two islanders you find most attractive.”
Joe was then seen kissing Molly, who split from compatriot Callum Jones in September last year.
Georgia Steel put the cat between pigeons on Monday's episode of Love Island All Stars when she asked Molly Smith if she had ever kissed new bombshell Joe Garratt (Georgia pictured)
In a teaser at the end of the episode, the islanders were seen playing a steamy icebreaker game, with scenes airing in Tuesday's episode and Molly kissing Joe
Laughing, Georgia leaned over to Molly as they sat next to each other and asked, “Was that the first time, Moll?”
Toby Aromolaran asked: “What was that for Georgia?”, to which she clarified: “I just asked Molly if it was her first kiss with Joe.”
The clip then shows Joe looking shocked while Molly sat in disbelief and shook her head.
Joe appeared on Love Island in 2019 as he vied for Lucie Donlan's heart, but soon sparked shock over his treatment of the surfer.
While he campaigned for her affection, the star came under fire from outside sources, accusing him of “manipulation and abuse” – which he later denied.
At the time he said: “I didn't manipulate or abuse her.” I'm disappointed that it was perceived that way because it wasn't like that at all.
“Maybe I worded something wrong and the cameras are on you 24/7. 'I may have made a mistake, but I'm only human.'
Joe's series was the same one that propelled Love Island kings Tommy Fury and Molly-Mae Hague to fame – with his Lucie love affair in the middle of their drama.
As part of the challenge, participants were asked: “Snog the two islanders you find most attractive.”
Joe was then seen kissing Molly, who split from compatriot Callum Jones (pictured) in September last year
Laughing, Georgia leaned over to Molly (pictured) as they sat next to each other and asked: “Was that the first time, Moll?”
The clip then shows Joe (pictured) looking shocked while Molly sat in disbelief and shook her head
Sources previously explained: “Joe was an important part of his series, but his story was somewhat overshadowed by the fact that he was alongside such iconic characters as Molly-Mae and Maura.” [Higgins].
“But since leaving the villa he's really carved out a niche for himself producing content for brands and remains at the center of the show – he's called the 'social rep' because he literally knows everyone.”
His arrival came after viewers rejoiced as Georgia S's “sneaky” ways finally came to light at Sunday night's dramatic PDA Awards.
The reality star, 25, was in a relationship with Callum, 27, before her head was turned by new arrival Tom Clare, 24, with whom she has a romantic history.
Viewers watched as Georgia, who is now dating 24-year-old Toby, passed on her flirty chats with Tom to the other islanders.
Especially for Callum, her lovers, when they spent a night together in the hideout and she told him that he was the only person she wanted to be with there.
However, the villa was rocked on Sunday when it emerged Georgia wasn't quite as honest as she claimed.
During the nominations for Most Insidious Islander at the PDA Awards, a video clip of every interaction between Georgia and Tom was broadcast throughout the villa.
Joe was seen arriving at the villa with twins Jess and Eve Gale, with the three being new bombshells
This included a clip in which she approaches Tom after the night with Callum and tells him she still likes him.
In another video of the couple playing a game of truth or dare, she can be seen telling Tom that she would rather be with him than Callum.
As viewers watched the whole thing unfold, her co-stars were unaware of her flirtatious antics with both contestants.
Love Island All Stars continues on Tuesday February 6th at 9pm on ITV2 and ITVX.
LOVE ISLAND ALL STARS: MEET THE CAST
Kaz Kamwi
AGE: 29
SERIES: 7
Why are you returning to the Love Island villa? To be completely honest, I really want to find love.
I had a great time last series, but I want to have an even better time.
How will you feel if you run into an ex in the villa or someone you previously dated from the series? The thing is: I'm a bad guy, so I'm going to handle this with as much grace as possible.
Georgia Harrison
AGE: 29
SERIES: 3
Why are you returning to the Love Island villa? This is the last year of my 20s so I want to go to the villa, have fun and hopefully meet someone I can fall in love with. I am lucky in the sense that I have everything I could want in my life, apart from love.
If you had to pick your top Islanders from Series 1 to 10, who would they be and why? Chris Taylor, he is hilarious and the main thing that attracts me is a man who can make me laugh. What a funny guy and like I said, I'm looking for someone to do TikTok with so I think he's up for something like that!
Georgia Steel
AGE: 25
SERIES: 4
Why are you returning to the Love Island villa? I'm 25, I have a house, a cat, a nice car – I have everything in life except a boyfriend, so why not just go for it.
You were brave and honest when you spoke openly about being cheated on by a former partner. How has this experience affected the way you approach dating now?
I now take this experience as a really positive reflection. I look at it as something I had to go through to become stronger and learn things in life so I can learn what I want in my next partner.
Molly Smith
AGE: 29
SERIES: 6
What do you need to know? Molly started her season as a Casa Amor bombshell and managed to turn Callum Jones's head.
It's thought she ended her relationship with Callum after three years because she “wanted to get engaged”, but the offer apparently didn't materialise.
Arabella Chi
AGE: 32
SERIES: 5
What do you need to know? Despite a brief appearance on her series, she has since made headlines with a number of high-profile romances, most recently with footballer Ruben Dias.
She has been linked to former French rugby player Yoann Huget and DJ Tom Zanetti. She also enjoyed a brief affair with fellow all-star Toby Aromolaran.
Tom Clare
AGE: 24
SERIES: 9
Why are you returning to the villa?
I found love last time, so I'm back and ready to try again.
What will you do differently this time?
Last time I did exactly what I wanted and got the girl I wanted, so no, I wouldn't do anything differently.
Why do you think the villa is the perfect place to find love?
When you're with someone 24/7, you really get to know them. It can be such a foreign environment that you really get to know someone in a short period of time. It's Love Island – it's the best place!
Casey O'Gorman
AGE: 27
SERIES: 9
Why are you returning to the Love Island villa? I didn't find love the first time, so I hope it brings luck the second time.
I had the most amazing experience before so take me back to this villa.
Who do you have your eye on? I'm definitely keeping an eye on Molly. I really think it gets a 10 out of 10. Georgia H too – I know her and we had a good time together. It will be interesting to see if it can evolve in some way.
Toby Aromolaran
AGE: 24
SERIES: 7
Why are you returning to the Love Island villa? If I'm single and Love Island is a chance for me, how could you turn down the chance to find love again?!
You had a long-term relationship with Chloe Burrows. How do you think she will react when she hears that you are going to the villa? I don't know how she would take it. We will always love each other and I think she would wish me good luck as I would definitely do the same.
Chris Taylor
AGE: 33
SERIES: 5
Why are you returning to the Love Island villa? The last time I was there was only 15 days, so I want to do it again and enjoy it all again. I'm 33 now and making progress slowly – I'm getting ear hair! It would be nice to have a girl to trim my ears!
How was the Barbie movie made? I was invited to an afterparty by Margot Robbie and ended up at an afterparty with her. I panicked and started talking to her just because I was having really stupid conversations. I can only assume that my silly conversation made an impression on Margot Robbie. 18 months later I received an email from Warner Brothers.
Anton Danyluk
AGE: 29
SERIES: 5
Why are you returning to the Love Island villa? For me it was a piece of cake. I got the call and it's a once-in-a-lifetime opportunity and probably the best summer I've ever had in my life. Getting the chance to do it twice will be incredible.
Why do you think the Love Island Villa is the perfect place to find love?
I think this time things will be different on Love Island: All Stars as we all understand what it's like to go on Love Island and the only thing missing now is finding a partner.
Callum Jones
AGE: 27
SERIES: 6
What do you need to know? Callum caused shockwaves on his show when he ended his romance with Shauna Phillips and got back together with Molly Smith in Casa Amor.
The couple had a three-year relationship and even moved in together in Manchester, but split last year, months before an awkward reunion in the Love Island All Stars villa.
Josh Ritchie
AGE: 29
SERIES: 1
What do you need to know? Joshua was one of the first Islanders in 2015 and has since made a name for himself on reality TV shows like Ex on the Beach and Celebs Go Dating – and for his high-profile romances.
He dated fellow All Stars star Georgia Harrison and Geordie Shore star Charlotte Crosby.
Sophie Piper
AGE: 24
SERIES: 6
Why are you returning to the famous Love Island villa?
I had a fun experience the first time, but I didn't go all the way and find love, so I would like to find someone this time.
What will you do differently this time?
I'm pretty laid back and don't want any drama, so I think I'll do it in a similar way this time. I'm a one-man girl.
Why do you think the villa is the perfect place to find love?
It is a once-in-a-lifetime experience and not something you experience every day.
Joanna Chimonides
AGE: 27
SERIES: 5
What do you need to know?
Viewers will remember how Joanna hooked up with her ex-boyfriend Michael Griffiths after they met at Casa Amor, which broke his then-partner Amber Gill's heart.
But Amber won the series and the £50,000 cash prize with Greg O'Shea after fans were furious at the way she was treated by Michael.
Entering the show for the second time, Joanna, who dated England footballer Ben Chilwell, has vowed not to play it safe – and will step on her toes if necessary.